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Im not sure if its related, but the timing seems to coincide. While the exact mechanism behind the link between glutathione and headaches is not yet fully understood, it is thought to be related to changes in blood flow and intracranial pressure

Foods and Beverages that May Interfere Some foods and drinks reduce glutathiones absorption or reduce its effectiveness as they increase oxidative stress in the body

Their use in Parkinson's is considered off-label and experimental

Persistent bacterial infections, antibiotic treatment failure, and microbial adaptive evolution

If evening injection alone does not fully resolve nausea, the next adjustment is dietary